Electrochemical Supercapacitors

Name: Electrochemical Supercapacitors
Brand: Springer Science+Business Media
SKU: 9780306457364
Price: 436.76 EUR
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Scientific Fundamentals and Technological Applications

Автор: B. E. Conway

Език:

Корици: С твърди корици

Издател: Springer Science+Business Media

Наличност: Външен склад

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The first model for the distribution of ions near the surface of a metal electrode was devised by He...

Информация за книгата

Автор

B. E. Conway

Език

Английски език

Корици

Книга - С твърди корици

Издадена

1999

страници

698

EAN

9780306457364

ISBN

0306457369

Enbook ID

01378874

Издател

Springer Science+Business Media

Теглоt

1196

Размери

164 x 235 x 51

Пълно описание

The first model for the distribution of ions near the surface of a metal electrode was devised by Helmholtz in 1874. He envisaged two parallel sheets of charges of opposite sign located one on the metal surface and the other on the solution side, a few nanometers away, exactly as in the case of a parallel plate capacitor. The rigidity of such a model was allowed for by Gouy and Chapman inde pendently, by considering that ions in solution are subject to thermal motion so that their distribution from the metal surface turns out diffuse. Stern recognized that ions in solution do not behave as point charges as in the Gouy-Chapman treatment, and let the center of the ion charges reside at some distance from the metal surface while the distribution was still governed by the Gouy-Chapman view. Finally, in 1947, D. C. Grahame transferred the knowledge of the struc ture of electrolyte solutions into the model of a metal/solution interface, by en visaging different planes of closest approach to the electrode surface depending on whether an ion is solvated or interacts directly with the solid wall. Thus, the Gouy-Chapman-Stern-Grahame model of the so-called electrical double layer was born, a model that is still qualitatively accepted, although theoreti cians have introduced a number of new parameters of which people were not aware 50 years ago.

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Electrochemical Supercapacitors

Scientific Fundamentals and Technological Applications

Информация за книгата

Пълно описание

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