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Книга Iminopropadienones Majed Shtaiwi

Iminopropadienones

The thermal generation and chemistry of Iminopropadienone

Автор: Majed Shtaiwi
Език: Английски език
Корици: С меки корици
Издател: LAP Lambert Academic Publishing
Наличност: Налично при издателя, по поръчка
Изпращаме след 17-27 дни
81.37 € 159.15 лв
This book describes the thermal fragmentation of heterocycles to give extended cumulenes called imin...

Информация за книгата

Автор
Majed Shtaiwi
Език
Английски език
Корици
Книга - С меки корици
Издадена
2012
страници
236
EAN
9783848405251
Enbook ID
07090442
Издател
LAP Lambert Academic Publishing
Теглоt
368
Размери
150 x 220 x 14

Пълно описание

This book describes the thermal fragmentation of heterocycles to give extended cumulenes called iminopropadienones, observed by infrared spectroscopy at 8 K and trapped by preparative flash vacuum pyrolysis (FVP). Chapter 1 describes the generation of iminopropadienones from Meldrum's acid derivatives. Chapter 2 describes the generation of 2,6-diflourophenyl iminopropadienone from 3- (2,6-difluorophenyl)isoxazolo[5,4-d]pyrimidine-4(5H)-one and a comparison with the generation of the same iminopropadienone from the Meldrum's acid derivative. Chapter 3 pyridopyrimidinones and a novel mesoionic compound (pyridopyrimidin-l-ium-2-olate) were used as precursors to generate iminopropadienones through flash vacuum pyrolysis. In Chapter 4, X-ray crystallography as well as theoretical calculations are used to investigate the unusual structural characteristics of Meldrum's acid derivatives used as precursors of iminopropadienones. These molecules were found to have zwitterionic and non-planar structures.

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