Magnetic Functions Beyond the Spin-Hamiltonian

Name: Magnetic Functions Beyond the Spin-Hamiltonian
Brand: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
SKU: 9783540260790
Price: 343.85 EUR
Availability: InStock

Автор: David M. P. Mingos

Език:

Корици: С твърди корици

Издател: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG

Наличност: Външен склад в ограничено количество

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Using the spin-Hamiltonian formalism the magnetic parameters are introduced through the components o...

Информация за книгата

Автор

David M. P. Mingos

Език

Английски език

Корици

Книга - С твърди корици

Издадена

2005

страници

278

EAN

9783540260790

ISBN

354026079X

Enbook ID

01560695

Издател

Springer-Verlag Berlin and Heidelberg GmbH & Co. KG

Теглоt

1300

Размери

155 x 235 x 22

Пълно описание

Using the spin-Hamiltonian formalism the magnetic parameters are introduced through the components of the Lambda-tensor involving only the matrix elements of the angular momentum operator. The energy levels for a variety of spins are generated and the modeling of the magnetization, the magnetic susceptibility and the heat capacity is done. Theoretical formulae necessary in performing the energy level calculations for a multi-term system are prepared with the help of the irreducible tensor operator approach. The goal of the programming lies in the fact that the entire relevant matrix elements (electron repulsion, crystal field, spin-orbit interaction, orbital-Zeeman, and spin-Zeeman operators) are evaluated in the basis set of free-atom terms. The modeling of the zero-field splitting is done at three levels of sophistication. The spin-Hamiltonian formalism offers simple formulae for the magnetic parameters by evaluating the matrix elements of the angular momentum operator in the basis set of the crystal-field terms. The magnetic functions for dn complexes are modeled for a wide range of the crystal-field strengths.

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Magnetic Functions Beyond the Spin-Hamiltonian

Информация за книгата

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