Main Group Compounds with π-Conjugated Nitrogen Support

Name: Main Group Compounds with &#960;-Conjugated Nitrogen Support
Brand: VDM Verlag
SKU: 9783639187793
Price: 50.9 EUR
Availability: InStock

Автор: Julie S. O'Brien

Език:

Корици: С меки корици

Издател: VDM Verlag

Наличност: Налично при издателя, по поръчка

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Ligand design, for the purpose of stabilizing transition metal complexes or unusual valencies of mai...

Информация за книгата

Автор

Julie S. O'Brien

Език

Английски език

Корици

Книга - С меки корици

Издадена

2009

страници

120

EAN

9783639187793

ISBN

3639187792

Enbook ID

06826915

Издател

VDM Verlag

Теглоt

186

Размери

152 x 229 x 7

Пълно описание

Ligand design, for the purpose of stabilizing transition metal complexes or unusual valencies of main group elements, is the focus of this book. Consequently, a great deal of thought has been invested in the design of organic molecules specifically tailored for this purpose. This research, therefore, provides synthetic routes to practical ligands which can fill this niche. The design of six-membered, singlet, N-heterocyclic carbenes for the stabilization of transition metal centers constitutes the first important area of current ligand synthesis and development. The related main group chemistry is pushed forward by exploring the further applicability of the developed ligands in stabilizing divalent and trivalent main group element centers. A catalytic route to produce quantitative yields of a wide variety of guanidines and amidines, two more classes of synthetically relevant ligands, are also presented. This work will outline and elaborate on the synthetic routes useful to organic, inorganic and main group chemists in creating these novel ligands, main group centers and metal complexes.

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Main Group Compounds with &#960;-Conjugated Nitrogen Support

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Main Group Compounds with π-Conjugated Nitrogen Support