Optical Studies in Liquids and Solids

Name: Optical Studies in Liquids and Solids
Brand: Springer-Verlag New York Inc.
SKU: 9781468487268
Price: 59.27 EUR
Availability: InStock

Автор: D. V. Skobel tsyn

Език:

Корици: С меки корици

Издател: Springer-Verlag New York Inc.

Наличност: Външен склад в ограничено количество

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59.27 € 115.92 лв

The study of the vibrations of polyatomic molecules has recently turned into one of the most widespr...

Информация за книгата

Автор

D. V. Skobel tsyn

Език

Английски език

Корици

Книга - С меки корици

Издадена

2014

страници

266

EAN

9781468487268

ISBN

1468487264

Enbook ID

05181923

Издател

Springer-Verlag New York Inc.

Теглоt

695

Размери

210 x 279 x 16

Пълно описание

The study of the vibrations of polyatomic molecules has recently turned into one of the most widespread and powerful methods of studying molecular structure. These vibrations ap pear directly in the infrared absorption spectra and Raman spectra of gases, liquids, and solids. A measurement of the number of bands in addition to their positions (frequencies or wavelengths) offers the possibility of obtaining a great deal of important information regarding the geometric and mechanical properties of the molecules, the types of chemical bonds, and so forth. It is now quite difficult to list the vast number of specific problems solved by measuring vibrational fre quencies. As a result of the successful development of research methods and the widespread applica tion of vibrational spectra in analyzing the structures of molecules and the constitution of ma terials, it now becomes necessary to develop the theory of molecular vibrations further. Existing theory, of course, is based on the assumption of the harmonicity of molecular vi brations, which, strictly speaking, is not justified experimentally. The anharmonicity of the molecular vibrations has therefore to be taken into account by introducing appropriate approxi mations. Thus, in carrying out calculations on the vibrations of polyatomic molecules, one uses the force constants calculated from the observed frequency values. However, as a result of the anharmonicity of the vibrations, the values of the observed frequencies differ from the harmonic values, and the force constants used therefore differ from the true ones, i. e.

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