Книга Solid Hydrogen Jan Kranendonk

Solid Hydrogen

Theory of the Properties of Solid H2, HD, and D2

Автор: Jan Kranendonk
Език: Английски език
Корици: С меки корици
Наличност: Външен склад
Изпращаме след 8-11 дни
52.78 103.24 лв
The solid molecular hydrogens are the simplest and most fundamental molecular solids. Except at ultr...

Информация за книгата

Автор
Език
Английски език
Корици
Книга - С меки корици
Издадена
2013
страници
306
EAN
9781468443035
ISBN
1468443038
Enbook ID
02253818
Теглоt
481
Размери
152 x 229 x 18

Пълно описание

The solid molecular hydrogens are the simplest and most fundamental molecular solids. Except at ultrahigh pressures on the order of a few mega bars, where a transition to a metallic, atomic phase is expected, these solids are true molecular crystals in which the molecules retain their identity with properties not too different from those of the free molecules. At energies below the electronic excitation energy, the thermal and spectroscopic pro perties of these solids are determined by the translational, rotational, and intramolecular vibrational motions of the interacting molecules. The theo retical analysis of the solid-state properties in terms of the free molecules and the intermolecular interactions forms the main topic of this book. The available detailed knowledge of the properties of the free molecules makes it feasible to carry out this program to a large extent on the basis of first principles, and this is one of the attractive features of these systems. The solid hydrogens are dominated by quantum effects, the most out standing property being that the rotation of the molecules is free down to the lowest temperatures, in the sense that the rotational quantum number J characterizing the rotational motion of the free molecules remains a good quantum number in all of the solid-state phases except at ultrahigh pressures.

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